Methyl 4-(1H-benzimidazol-2-yl)benzoate trihydrate

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Methyl 4-(1H-benzimidazol-2-yl)benzoate trihydrate

The title compound, C(15)H(12)N(2)O(2)·3H(2)O, has been prepared from the reaction of a Schiff base of benzene-1,2-diamine and iron perchlorate at room temperature. The dihedral angle between the benzimidazole ring and the 4-substituted benzene ring is 0.47 (3)°. Hydrogen bonding involving water mol-ecules, imidazole N, imidazole imine H and ester O atoms stabilizes the crystal structure.

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4-(1H-Benzimidazol-2-ylmeth­oxy)-3-eth­oxy­benzaldehyde trihydrate

In the title compound, C(17)H(16)N(2)O(3)·3H(2)O, the dihedral angle between the mean planes of the benzene and benzimidazole systems is 26.2 (3)°. These groups are slightly twisted around the eth-oxy-methane unit [C-C-O-C torsion angle = 177.64 (15)°]. The crystal packing is stabilized by N-H⋯O, O-H⋯N and O-H⋯O hydrogen-bond inter-actions involving the water mol-ecules. Weak π-π stacking inter...

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2-(1H-Benzimidazol-2-yl)-4-nitro­phenol

The title compound, C(13)H(9)N(3)O(3), was prepared by the reaction of 5-nitro-salicyl-aldehyde with 1,2-diamino-benzene in methanol. The whole mol-ecule is approximately planar, with a mean deviation from the plane defined by the non-H atoms of 0.0311 (4) Å, and with a dihedral angle between the benzene ring and the benzimidazole ring system of 1.1 (3)°. An intra-molecular O-H⋯N hydrogen bond ...

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2-Methyl-6-(6-methyl-1H-benzimidazol-2-yl)phenol–2-methyl-6-(5-methyl-1H-benzimidazol-2-yl)phenol (3/1)

The title compound, 0.75C(15)H(14)N(2)O·0.25C(15)H(14)N(2)O, is a co-crystal of 2-methyl-6-(6-methyl-1H-benzimidazol-2-yl)phenol as the major component and 2-methyl-6-(5-methyl-1H-benz-imidazol-2-yl)phenol as the minor component. The refined site-occupancy ratio is 0.746 (4)/0.254 (4). The conformations of both components are identical except for that of the methyl substituent on the benzene ri...

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4-(1H-Benzimidazol-2-yl)benzonitrile

The mol-ecule of the title compound, C(14)H(9)N(3), is essentially planar, the dihedral angle formed by the benzimidazole ring system with the benzene ring being 3.87 (3)°. In the crystal packing, mol-ecules are linked into zigzag chains running parallel to the b axis by inter-molecular N-H⋯N hydrogen-bond inter-actions.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2010

ISSN: 1600-5368

DOI: 10.1107/s1600536810039188